One of Hollywood’s biggest couples is separating. Angelina Jolie has filed for divorce from Brad Pitt.

Update 2: Adele, who’s best known for her tragic breakup songs, dedicated last night’s show in New York to Pitt and Angelina. The singer says she was “genuinely” shocked and saddened by the news:

Update: Brad Pitt says in a statement: “I am very saddened by this, but what matters most now is the well-being of our kids. I kindly ask the press to give them the space they deserve during this challenging time.”

Jolie is asking for physical custody of all six of their children. According to TMZ, the decision to divorce Brad came down to the way he takes care of the kids.

“Sources connected with the couple tell us … Angelina’s decision to file has to do with the way Brad was parenting the children … she was extremely upset with his methods,” they write. “We’re told there was no alleged ‘third person’ … her decision to file was solely over Brad’s interaction with their children.”

Jolie wants Pitt to have visitation rights but “does not want Brad to have joint physical custody … only joint legal custody.”

Jolie and Pitt have been together since 2004 and married in 2014.

Many would argue that the two actors are were the biggest couple in Hollywood. Besides their very successful solo careers, the pair also starred in a couple films together — Mr. and Mrs. Smith and the Jolie-directed By the Sea.

They’ve been together for so long that the news of their relationship’s will definitely come as a shocker to the public.

Pitt was Jolie’s third husband — she was previously married to Jonny Lee Miller and Billy Bob Thornton. Pitt was previously married to Jennifer Aniston.

Love is dead, etc. etc.